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Diamonds Created at Room Temperature in North Carolina State University Lab

Dec 1, 2015 10:03 AM   By Rapaport News
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RAPAPORT... Researchers at North Carolina State University (NC State) have discovered a method of producing diamond at room temperature and ambient atmospheric pressure in air, identifying a third and previously unknown form of carbon.

While the two known ‘phases’ of solid carbon – distinct forms of the same material – are graphite and diamond, the experts said they have created another phase. Known as Q-carbon, it is ferromagnetic, harder than diamond and glows in the dark, the university said in a statement.

Researchers have developed a technique for using Q-carbon to make diamond-related structures. The substance could be used to create a “variety of single-crystal diamond objects,” the statement said November 30.

“We’ve now created a third solid phase of carbon,” according to Jay Narayan, the John C. Fan distinguished chair professor of materials science and engineering at NC State and lead author of three papers describing the work. “The only place it may be found in the natural world would be possibly in the core of some planets.”

The creation process starts with a substrate such as sapphire, glass or a plastic polymer. The substrate is then coated with amorphous carbon which does not have a regular, well-defined crystalline structure.

The carbon is then hit with a single laser pulse lasting approximately 200 nanoseconds. During this pulse, the temperature of the carbon is raised to around 3,727 degrees Celsius and then rapidly cooled. The process takes place in the same pressure as the surrounding air and leaves a film of Q-carbon, which can be controlled to be between 20 nanometers and 500 nanometers thick.

By using different substrates and changing the duration of the laser pulse, the researchers can also control how quickly the carbon cools, the university said. By changing the rate of cooling, they are able to create diamond structures within the Q-carbon.

“These diamond objects have a single-crystalline structure, making them stronger than polycrystalline materials,” Narayan said. “We’re basically using a laser like the ones used for laser eye surgery. So, not only does this allow us to develop new applications, but the process itself is relatively inexpensive.”

One of the new substance’s additional benefits could be for new electronic display technologies, he added. NC State has filed two provisional patents for the Q-carbon and diamond-creation techniques, the statement said.

The work, by Narayan and NC State PhD student Anagh Bhaumik, was published October 7 in the journal APL Materials, while a second article was slated to be published in the Journal of Applied Physics November 30.
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